| Description |
1 online resource |
| Contents |
Front Matter -- From Anion Recognition to Organocatalytic Chemical Reactions / Friedemann Dressler, Peter R. Schreiner -- Anion Recognition and Binding Constant Determination / Edward G Sheetz, David Van Craen, Amar H Flood -- (Thio)urea and Squaramide-Catalyzed Anion-Binding Catalysis with Halogen Anions / Matthew A Horwitz, Veronique Gouvenour -- Chiral Ureas, Thioureas, and Squaramides in Anion-Binding Catalysis with Co-catalytic Bronsted/Lewis Acids / Adam Trotta, Eric N Jacobsen -- Anion-Binding Catalysis with Other Anions / Sankash Mitra, Santanu Mukherjee -- Silanediols, Phosphoramides, and Other OH- and NH-Based H-Donor Catalysts / Alexandria Leveille, Anita Mattson -- 1,2,3-Triazoles and 1,2,3-Triazolium Ions as Catalysts / Kohsuke Ohmatsu, Takashi Ooi -- Quaternary Ammonium, Phosphonium, and Tertiary Sulfonium Salts as Hydrogen-Bonding Catalysts / Seiji Shirakawa -- Assisted and Dual Anion Binding in Amino and Nucleophilic Catalysis / Efraim Reyes, Qui-Nhi Duong, Liher Prieto, Olga Garcia Mancheno, Jose L Vicario -- Anion-Binding Catalysis by Halogen, Chalcogen, Pnictogen, and Tetrel Bonding / Raffaella Papagna, Lukas Vogel, Stefan M Huber -- New Trends and Supramolecular Approaches in Anion-Binding Catalysis / Maria C Perez-Aguilar, Melania Gomez-Martinez, Jan Kuhlmann, Olga Garcia Mancheno. |
| Bibliography |
Includes bibliographical references and index. |
| Summary |
Explores the potential of new types of anion-binding catalysts to solve challenging synthetic problems Anion-Binding Catalysis introduces readers to the use of anion-binding processes in catalytic chemical activation, exploring how this approach can contribute to the future design of novel synthetic transformations. Featuring contributions by world-renowned scientists in the field, this authoritative volume describes the structure, properties, and catalytic applications of anions as well as synthetic applications and practical analytical methods. In-depth chapters are organized by type of catalyst rather than reaction type, providing readers with an accessible overview of the existing classes of effective catalysts. The authors discuss the use of halogens as counteranions, the combination of (thio)urea and squaramide-based anion-binding with other types of organocatalysis, anion-binding catalysis by pnictogen and tetrel bonding, nucleophilic co-catalysis, anion-binding catalysis by pnictogen and tetrel bonding, and more. Helping readers appreciate and evaluate the potential of anion-binding catalysis, this timely book: Illustrates the historical development, activation mode, and importance of anion-binding in chemical catalysis Explains the analytic methods used to determine the anion-binding affinity of the catalysts Describes catalytic and synthetic applications of common NH- and OH-based hydrogen-donor catalysts as well as C-H triazole/triazolium catalysts Covers amino-catalysis involving enamine, dienamine, or iminium activation approaches Discusses new trends in the field of anion-binding catalysis, such as the combination of anion-binding with other types of catalysis Presenting the current state of the field as well as the synthetic potential of anion-binding catalysis in future, Anion-Binding Catalysis is essential reading for researchers in both academia and industry involved in organic synthesis, homogeneous catalysis, and pharmaceutical chemistry. |
| Subject |
Catalysis.
|
|
Anions.
|
|
Catalysis |
|
Anions |
|
Catalyse. |
|
Anions. |
|
Anions |
|
Catalysis |
| Added Author |
García Mancheño, Olga, editor.
|
| ISBN |
9783527830664 (electronic bk. ; oBook) |
|
3527830669 (electronic bk. ; oBook) |
| Standard No. |
10.1002/9783527830664 doi |
|
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